Enhancing the Hydrolysis of Africa Pear Seed Oil
DOI:
https://doi.org/10.38124/ijsrmt.v1i3.17Keywords:
Hydrolysis, Fatty Acids, Pretreatment, Catalyst, PhysicochemicalAbstract
Recent trend in terms of waste seed oil application has shown vast industrial relevance. Therefore, the high fatty acid concentration of African Pear (Dacryodes edulis) Seed-oil (APSO) is the reason for its utilization, thereby according it the possible potential as feedstock for industrial applications. However, pretreatment of the oil extract is key to its functionality as feedstock in industrial processes. Therefore the process of hydrolysis as a pretreatment route based on the types of catalysts, and a variety of reaction circumstances, including concentration, temperature as well as reaction time was adopted and characterization was affirmed with FTIR and GC-MS analytical methods. The results showed that the highest percentage Free Fatty Acid (% FFA) hydrolysis was obtained at optimum concentration (2 M), temperature (60 oC) and reaction time (2 hrs). Rapid hydrolysis was observed at 1.5 M for both ethanolic KOH and NaOH, thereby reporting a percentage yield of 70.58 % and 63.37 % of the % FFA for KOH and NaOH respectively. Further characterization findings by GC-MS confirmed a positive identification of % FFA composition. Likewise the FTIR analysis also exhibited high carboxylic acid peak absorption for NaOH and KOH catalyst at 1781 cm-1 and 1179 cm-1 respectively. Therefore, the result is a pointer that catalyst and the choice of a suitable reaction condition has the potential to influence the rate of hydrolysis in oil.
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References
. Ezeonu, C. S., Tagbo, R., Anike, E. N., Oje, O. A., and Onwurah, I. N. E. (2012). Biotechnological Tools for Environmental Sustainability: Prospects and Challenges for Environments in Nigeria—A Standard Review. Biot. Res. Inter,, 1–26.
. Ibanga O. I., Okon D. E., and Udofot J. E. (2014). Extraction, Characterization of African Pear (Dacryodes Edulis) Oil and its Application in Synthesis and Evaluation of Surface Coating Driers. Inter. J. Ad. Res. Chem. Sc. 1(4), 14-22.
. Follegatti-Romero LA, Piantino CR, Grimaldi R, and Cabral FA (2009) Supercritical CO2 extraction of omega-3 rich oil from sacha inchi (Plukenetia volubilis L.) seeds. J Supercrit Fluid 49:323–329,
. Boussetta N, Soichi E, Lanoiselle´ JL, and Vorobiev E (2014) Valorization of oilseed residues: extraction of polyphenols from flaxseed hulls by pulsed electric field. Ind Crop Prod, 52:347–353.
. Kaseke, T., Opara, U. L., and Fawole, O. A. (2021). Novel seeds pretreatment techniques: effect on oil quality and antioxidant properties: a review. J. Food Sci. Tech.. doi:10.1007/s13197-021-04981-1.
. Vermaak, I., Kamatou, G. P. P., Komane-mofokeng, B., Viljoen, A. M., and Beckett, K. (2011) African seed oils of commercial importance- Cosmetic applications. S Afr J Bot 77:920–933.
. Pateraki, C., Papadaki, A., Koutinas, A., & Kachrimanidou, V. (2019). Biorefinery Engineering. Comp. Biot., 879–892. doi:10.1016/b978-0-444-64046-8.00107-5.
. Salimon, J., Abdullah, B., and Salih, N. (2011). Hydrolysis optimization and characterization study of preparing fatty acids from Jatropha curcas seed oil. Chem. Cen. J., 5(1), 67.
. Rukmini, A., and Raharjo S (2010). Pattern of Peroxide Value Changes in Virgin Coconut Oil (VCO) Due to Photo-Oxidation Sensitized by Chlorophyll. J. Amer. Oil Chem.’ Soc., 87:1407-1412.
. Serri, N. A., Kamarudin, A. H., and Abdul Rahaman, S. N (2008). Preliminary studies for production of fatty acids from hydrolysis of cooking palm oil using C. rugosa lipase. J. Phy. Sci., 19:79-88.
. Pinto, J. S. S., and Lanças, F. M (2006). Hydrolysis of corn oil using subcritical water. J. Braz. Chem. Soc., 17:85-89.
. Fakhfakh, J., Ben-Youssef, S., Naushad, M., and Allouche, N. (2019). Different Extraction Methods, Physical Properties and Chemical Composition of Date Seed Oil. Energy Generation Using Reverse Electrodialysis, 125–153. doi:10.1007/978-3-030-11345-2_7.
. Akhlisah, Z. N., Yunus, R., Abidin, Z. Z., Lim, B. Y., and Kania, D. (2021). Pretreatment methods for an effective conversion of oil palm biomass into sugars and high-value chemicals. Bio. and Bioenergy, 144, 105901. doi:10.1016/j.biombioe.2020.10590.
. Perera, D. N., Hewavitharana, G. G., and Navaratne, S. B. (2020). Determination of Physicochemical and Functional Properties of Coconut Oil by Incorporating Bioactive Compounds in Selected Spices. J. of Lip., 1–11. doi:10.1155/2020/8853940.
. Guderjan, M., Elez-Martı´nez, P., and Knorr, D. (2007) Application of pulsed electric field at oil yield and content of functional food ingredients at the production of rapeseed oil. Innov Food Sci Emerg Technol 8:55–62.
. Zhou, Y., Fan, W., Chu, F., and Pei, D. (2016) Improvement of the flavor and oxidative stability of walnut oil by microwave pretreatment. J Am Oil Chem Soc. 93:1563–1572.
. Guneser, A. B., and Yilmaz, E. (2017) Effects of microwave roasting on the yield and composition of cold pressed orange seed oils. Grasas Aceites, 68:1–10.
. Kittiphoom, S., and Sutasinee, S. (2015) Effect of microwaves pretreatments on extraction yield and quality of mango seed kernel oil. Int Food Res J. 22:960–964.
. Scrimgeour, C. (2005). Chemistry of fatty acid. In Bailey’s industrial oil and fat products. Volume 5. 6 edition. Edited by: Shahidi F. Wiley, Hoboken:1-43.
. Kywe, T. T., Oo, M. M. (2009). Production of biodiesel from Jatropha oil (Jatropha curcas) in pilot plant. Proceeding of World Academy of Science and Technology, 38:481-487.
. Berchmans, H. J., and Hirata, S, (2008). Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids. Biore. Techn., 99:1716-1721.
. Nde, and Foncha. (2020). Optimization Methods for the Extraction of Vegetable Oils: A Review. Proc., 8(2), 209.
. Ðurd¯evic´ S., Milovanovic´ S., S ˇ avikin K., Ristic´ M., Menkovic´ N., Pljevljakusˇic´ D., Petrovic´a S., and Bogdanovic´ A. (2017) Improvement of supercritical CO2 and n-hexane extraction of wild growing pomegranate seed oil by microwave pretreatment. Ind Crop Prod. 104:21–27.
. Moradi, N., and Rahimi, M. (2018) Effect of simultaneous ultrasound/pulsed electric field pretreatments on the oil extraction from sunflower seeds. Sep Sci Technol 53:1–12.
. Mohseni, N. M., Mirzaei, H., and Moghimi, M. (2020a) Optimized extraction and quality evaluation of niger seed oil via microwave-pulsed electric field pretreatments. Food Sci Nutr. 8:1383–1393.
. A.O.A.C. (2000). 17th edn, Official method 920. 159 – Iodine absorption number of oils and fats / I.S.I. Handbook of Food Analysis ( Part XIII) – 1984 page 76).
. Mahesar, S. A., Sherazi, S. T. H., Khaskheli, A. R., Kandhro, A. A., and uddin, S. (2014). Analytical approaches for the assessment of free fatty acids in oils and fats. Anal. Methods, 6(14), 4956–4963.
. Liang, M.-Y., Chen, Y., Banwell, M. G., Wang, Y., and Lan, P. (2018). Enzymatic Preparation of a Homologous Series of Long-Chain 6-O-Acylglucose Esters and Their Evaluation as Emulsifiers. J. Agri. Food Chem., 66(15), 3949–3956.
. Adams, R. P. (1995). Identification of Essential Oil Components by Gas Chromatography/Mass Spectrometry. Allured Publishing Corporation; Carol Stream, IL, USA.
. Noor, I. M., and Hasan, M. (2003). Ramachandran KB: Effect of operating variable on the hydrolysis rate of palm oil by lipase. Proc. Biochem. 39:13-20.
. Rooney, D., Weatherly, L. R. (2001). The effect of reaction conditions upon lipase catalysed hydrolysis of high oleate sunflower oil in a stirred liquid-liquid reactor. Proc. Biochem. 36:947-953.
. Ikhuoria, E. U., Maliki, M., (2007). Characterization of avocado pear (Persea americana) and Africa pear (Dacryodes edulis) extracts. African J. Biotech. 7, 950-954.
. Umoti, U., Okyi, D. A., (1987). Characteristics and composition of oil and cake of African pear. J. Sci., Food Agr. 38, 67 – 72.
. Sabita Aryal, Liu Ye Qiang (2024), Implications of Adnexal Invasions in Primary Extramammary Paget’s Disease: A Systematic Review. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR2251, 1179-1184. DOI: 10.38124/ijisrt/IJISRT24APR2251. https://www.ijisrt.com/implications-of-adnexal-invasions-in-primary-extramammary-pagets-disease-a-systematic-review
. Yogesh Kumar. C (2024), A Study to Evaluate Psychological Distress and Self-Esteem Among Patients with Hemodialysis. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24MAR1998, 2491-2501. DOI: 10.38124/ijisrt/IJISRT24MAR1998. https://www.ijisrt.com/a-study-to-evaluate-psychological-distress-and-selfesteem-among-patients-with-hemodialysis
. ZEWAR Shah, SHAN Zhiyong, Adnan . (2024), Enhancements in Immediate Speech Emotion Detection: Harnessing Prosodic and Spectral Characteristics. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR872, 1526-1534. DOI: 10.38124/ijisrt/IJISRT24APR872. https://www.ijisrt.com/enhancements-in-immediate-speech-emotion-detection-harnessing-prosodic-and-spectral-characteristics
. Mushtaq Ahmad Shah, Khomane Harish, Shradha ., Kutlu Hansda, Diksha Chowdhury, Sakshi Yadav (2024), Beyond Mobile Payments: Exploring the Evolution and Future of Fintech. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR259, 468-473. DOI: 10.38124/ijisrt/IJISRT24APR259. https://www.ijisrt.com/beyond-mobile-payments-exploring-the-evolution-and-future-of-fintech
. Vahid Hosseini, Seyed Masoud Ghoreishi Mokri, Dalia hafezghoran, Bahareh Karimi, Anastasia Aleksandrovna Anashkina, Anna Borisovna Yazykova (2024), Preparation and Identification of Magnetic Iron Nanoparticle based ona Natural Hydrogel and its Performance in Targeted Drug Delivery. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24MAY1088, 704-720. DOI: 10.38124/ijisrt/IJISRT24MAY1088. https://www.ijisrt.com/preparation-and-identification-of-magnetic-iron-nanoparticle-based-ona-natural-hydrogel-and-its-performance-in-targeted-drug-delivery
. M. T. Kanojiya, Ashish Fande, Payal Lokhande, Sanskruti Chokhandre, Tusharika Mahalle, Rishabh Sakhre, Aditya Kewade (2024), Design and Development of Multi-Featured Medical Stretcher. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24MAY1590, 902-905. DOI: 10.38124/ijisrt/IJISRT24MAY1590. https://www.ijisrt.com/design-and-development-of-multifeatured-medical-stretcher
. Jeremiah Mugambi Ananga, Samson Nyang’au Paul, Tobias Mwalili (2024), Technology Infrastructure and Business Performance of Commercial Banks in Kenya. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR1616, 1655-1663. DOI: 10.38124/ijisrt/IJISRT24APR1616. https://www.ijisrt.com/technology-infrastructure-and-business-performance-of-commercial-banks-in-kenya
. Jeremiah Mugambi Ananga, Tobias Mwalili, Samson Nyang’au Paul (2024), Technology Processes and Business Performance of Commercial Banks in Kenya. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR1615, 1589-1597. DOI: 10.38124/ijisrt/IJISRT24APR1615. https://www.ijisrt.com/technology-processes-and-business-performance-of-commercial-banks-in-kenya
. Soi Judith Cherono, Dr. Tobias Mwalili, Dr. Samson Nyang’au Paul (2024), Information Technology Skills and Firm Performance of Kenya Tea Producers Companies. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR1614, 1576-1588. DOI: 10.38124/ijisrt/IJISRT24APR1614. https://www.ijisrt.com/information-technology-skills-and-firm-performance-of-kenya-tea-producers-companies
. Soi Judith Cherono, Samson Nyang’au Paul, Tobias Mwalili (2024), Technology Communication and Firm Performance of Kenya Tea Producers Companies. International Journal of Innovative Science and Research Technology (IJISRT) IJISRT24APR1459, 1511-1521. DOI: 10.38124/ijisrt/IJISRT24APR1459. https://www.ijisrt.com/technology-communication-and-firm-performance-of-kenya-tea-producers-companies
. Suwarna Shukla, Prabhneet Singh (2024), Revolutionizing Supply Chain Management: Real-time Data Processing and Concurrency. IJISRT24MAY207, 23-30. DOI: 10.38124/ijisrt/IJISRT24MAY207. https://www.ijisrt.com/revolutionizing-supply-chain-management-realtime-data-processing-and-concurrency
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